金与王水反应的化学方式

2025-04-06 11:09:04
推荐回答(2个)
回答1:

王水是由1体积的浓硝酸和3体积的浓盐酸混合而成的(严格地说是在其混酸中hno3和hcl的物质的量之比为1∶3)。王水的氧化能力极强,称之为酸中之王。一些不溶于硝酸的金属,如金、铂等都可以被王水溶解。尽管在配制王水时取用了两种浓酸,然而在其混合酸中,硝酸的浓度显然仅为原浓度的¼(即已成为稀硝酸)。但为什么王水的氧化能力却比浓硝酸要强得多呢?这是因为在王水中存在如下反应:
hno3
+
3hcl
2h2o
+
cl2
+
nocl
因而在王水中含有硝酸、氯分子和氯化亚硝酰等一系列强氧化剂,同时还有高浓度的氯离子。
王水的氧化能力比硝酸强,金和铂等惰性金属不溶于单独的浓硝酸,而能溶解于王水,其原因主要是在王水中的氯化亚硝酰(nocl)等具有比浓硝酸更强的氧化能力,可使金和铂等惰性金属失去电子而被氧化:
au
+
cl2
+
nocl
=
aucl3
+
no↑
3pt
+
4cl2
+
4nocl
=
3ptcl4
+
4no↑
同时高浓度的氯离子与其金属离子可形成稳定的络离子,如[aucl4]-

[pt
cl6]2-:
aucl3
+
hcl
=
h[aucl4]
ptcl4
+2hcl
=
h2[pt
cl6]
从而使金或铂的标准电极电位减小,有利于反应向金属溶解的方向进行。总反应的化学方程式可表示为:
au
+
hno3
+
4hcl
=
h[aucl4]
+
no↑+
2h2o
3pt
+
4hno3
+
18hcl
=
3h2[pt
cl6]
+
4no↑+
8h2o
由于金和铂能溶解于王水中,人们的金铂首饰(黄金或白金)在被首饰加工商加工清洗时,常会在不知不觉中被加工商用这种方法偷取,损害消费者的利益

回答2:

金具有稳定性,不与任何化学物质发生反应,更不会融某液体。使镀金脱落,不是融入。

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