(2012?湖南模拟)乙醇是重要的化工原料和液体燃料,可以在一定条件下利用CO2与H2反应制得:2CO2(g)+6H

2025-04-07 01:42:52
推荐回答(1个)
回答1:

(1)可逆反应2CO2(g)+6H2(g)?CH3CH2OH(g)+3H2O(g)的平衡常数k=

c(CH3CH2OH)?c3(H2O)
c2(CO2)?c6(H2)

故答案为:
c(CH3CH2OH)?c3(H2O)
c2(CO2)?c6(H2)

(2)该反应正反应是放热反应,升高温度平衡向逆反应移动,平衡常数减小,即温度越高,平衡常数越小,温度T1>T2,故K1<K2,故答案为:<;
(3)a.生成1mol CH3CH2OH的同时,生成3mol H2O,都表示正反应速率,二者始终按1:3进行,不能说明到达平衡,故a错误;
b.可逆反应到达平衡时,各组分的物质的量不变,体系中各组份的物质的量浓度不随时间而变化,说明到达平衡,故b正确;
c.反应混合气体的总质量不变,容器的体积不变,密度始终不变,体系中混合气体的密度不随时间而变化,不能说明到达平衡,故c错误;
d.随反应进行混合气体总的物质的量减小,体系中气体的分子总数减少,体系中气体分子总数不随时间而变化,说明到达平衡,故d正确;
故答案为:bd;
(4)改变条件加快反应速率,同时平衡向正反应移动,可以增大CO2浓度或增大压强,反应速率加快,平衡向正反应移动氢气的转化率增大,
故答案为:增大CO2浓度或增大压强;
(5)由图象可知,反应物的总能量大于生成物的总能量,故该反应物为放热反应,
故答案为:放热;反应物的总能量大于生成物的总能量;
(6)负极反应氧化反应,乙醇在负极放电,酸性条件下生成二氧化碳与氢离子,电极反应式为:CH3CH2OH-12 e-+3H2O=2CO2+12H+
故答案为:CH3CH2OH-12 e-+3H2O=2CO2+12H+

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